| Rank | City | 2000 Population |
|---|---|---|
| 1 | Hayden | 889 |
| 2 | Tempe | 158,860 |
| 3 | Prescott Valley | 24,421 |
| 4 | Winkelman | 442 |
| 5 | Nogales | 20,900 |
| 6 | Peoria | 110,950 |
| 7 | Payson | 13,681 |
| 8 | Buckeye | 9,757 |
| 9 | Winslow | 9,549 |
| 10 | Safford | 9,241 |
| 11 | El Mirage | 8,375 |
| 12 | Chino Valley | 8,255 |
| 13 | Somerton | 7,563 |
| 14 | Bisbee | 6,231 |
| 15 | Sahuarita | 3,778 |
| 16 | Litchfield Park | 3,822 |
| 17 | Queen Creek | 3,244 |
| 18 | Superior | 3,258 |
| 19 | Parker | 3,124 |
| 20 | Youngtown | 3,020 |
| 21 | Clifton | 2,592 |
| 22 | Springerville | 1,974 |
| 23 | Lake Havasu City | 42,406 |
| 24 | Duncan | 812 |
| 25 | Wellton | 1,870 |
| 26 | Mammoth | 1,774 |
| 27 | Avondale | 37,257 |
| 28 | Bullhead City | 33,967 |
| 29 | Surprise | 32,348 |
| 30 | Jerome | 359 |
| 31 | Paradise Valley | 13,694 |
| 32 | Eloy | 10,512 |
| 33 | Sedona | 10,252 |
| 34 | Camp Verde | 9,486 |
| 35 | Cottonwood | 9,385 |
| 36 | Coolidge | 8,515 |
| 37 | Show Low | 7,905 |
| 38 | Globe | 7,473 |
| 39 | Page | 6,822 |
| 40 | Tolleson | 5,028 |
| 41 | Wickenburg | 5,895 |
| 42 | South Tucson | 5,514 |
| 43 | Guadalupe | 5,231 |
| 44 | Holbrook | 4,967 |
| 45 | Benson | 4,730 |
| 46 | Snowflake | 4,481 |
| 47 | Thatcher | 4,059 |
| 48 | Eagar | 4,044 |
| 49 | Cave Creek | 3,770 |
| 50 | Colorado City | 3,379 |
| 51 | Willcox | 3,741 |
| 52 | Pinetop-Lakeside | 3,605 |
| 53 | St. Johns | 3,554 |
| 54 | Dewey-Humboldt | 3,431 |
| 55 | Clarkdale | 3,400 |
| 56 | Quartzsite | 3,341 |
| 57 | Taylor | 3,220 |
| 58 | Carefree | 2,960 |
| 59 | Williams | 2,847 |
| 60 | Pima | 2,097 |
| 61 | Kearny | 2,263 |
| 62 | Star Valley | 2,019 |
| 63 | Gila Bend | 1,998 |
| 64 | Miami | 1,931 |
| 65 | Huachuca City | 1,754 |
| 66 | Kingman | 21,036 |
| 67 | Fountain Hills | 20,482 |
| 68 | Florence | 17,308 |
| 69 | Douglas | 16,592 |
| 70 | San Luis | 15,713 |
| 71 | Marana | 14,379 |
| 72 | Tombstone | 1,509 |
| 73 | Fredonia | 1,037 |
| 74 | Patagonia | 902 |
| 75 | Chandler | 179,577 |
| 76 | Tucson | 489,355 |
| 77 | Mesa | 402,853 |
| 78 | Phoenix | 1,326,997 |
| 79 | Glendale | 221,780 |
| 80 | Scottsdale | 204,285 |
| 81 | Gilbert | 117,306 |
| 82 | Yuma | 79,090 |
| 83 | Goodyear | 19,636 |
| 84 | Flagstaff | 53,095 |
| 85 | Casa Grande | 26,939 |
| 86 | Maricopa | 1,748 |
| 87 | Sierra Vista | 37,814 |
| 88 | Prescott | 34,352 |
| 89 | Oro Valley | 32,761 |
| 90 | Apache Junction | 32,087 |
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